Bromo(tetrahydrothiophene)gold(I)

Bromo(tetrahydrothiophene)gold(I) is a coordination complex of gold. It is related to the more commonly used chloro(tetrahydrothiophene)gold(I). Similarly, the tetrahydrothiophene ligand is labile and is readily substituted with other stronger ligands, to give linear gold bromide complexes.

Bromo(tetrahydrothiophene)gold(I)
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C4H8S.Au.BrH/c1-2-4-5-3-1;;/h1-4H2;;1H/q;+1;/p-1
    Key: DVTPJQDAZYEPPF-UHFFFAOYSA-M
  • Br[Au-][S+]1CCCC1
Properties
C4H8AuBrS
Molar mass 365.04 g·mol−1
Related compounds
Related compounds
 chloro(tetrahydrothiophene)gold(I), chloro(dimethyl sulfide)gold(I)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

This compound may be prepared by reaction of tetrabromoauric acid (formed from tetrachloroauric acid and hydrobromic acid) with tetrahydrothiophene.[1]

References
  1. Eiter, Lauren C.; Hall, Nathan W.; Day, Cynthia S.; Saluta, Gilda; Kucera, Gregory L.; Bierbach, Ulrich (2009). "Gold(I) Analogues of a Platinum–Acridine Antitumor Agent are only Moderately Cytotoxic but Show Potent Activity Against Mycobacterium Tuberculosis". Journal of Medicinal Chemistry. 52 (21): 6519–22. doi:10.1021/jm9012856. PMC 3176588. PMID 19803526.
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