Palladium tetrafluoride

Palladium (IV) fluoride, also known as palladium tetrafluoride, is the chemical compound of palladium and fluorine with the chemical formula PdF4. The palladium atoms in PdF4 are in the +4 oxidation state.[2][3]

Palladium(IV) fluoride
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/4FH.Pd/h4*1H;/p-4
    Key: TZSYMMIYHWWKKM-UHFFFAOYSA-J
  • [F-].[F-].[F-].[F-].[Pd]
Properties
F4Pd
Molar mass 182.41 g·mol−1
Appearance pink[1] or brick-red[2] crystalline solid
Related compounds
Other cations
 Platinum(IV) fluoride
Related compounds
 Palladium(II) fluoride
Palladium(II,IV) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Synthesis

Palladium tetrafluoride has been prepared by reacting palladium(II,IV) fluoride with fluorine gas at pressures around 7 atm and at 300 °C for several days.[1]

Reactivity

PdF4 is a strong oxidising agent and undergoes rapid hydrolysis in moist air.[1]

See also

References
  1. Rao, P. R.; Tressaud, A.; Bartlett, N. (1976). "The tetrafluorides of iridium, rhodium and palladium". J. Inorg. Nucl. Chem. 28: 23–28. doi:10.1016/0022-1902(76)80588-X.
  2. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 1152–1153. ISBN 978-0-08-037941-8.
  3. Housecroft, C. E.; Sharpe, A. G. (2008). Inorganic Chemistry (3rd ed.). Prentice Hall. pp. 788–789. ISBN 978-0-13-175553-6.
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