Krypton tetrafluoride

Krypton(IV) fluoride is a hypothetical inorganic chemical compound of krypton and fluorine with the chemical formula KrF4. At one time researchers though they made it, but the claim was discredited.[1] The compound is predicted to be difficult to make and unstable if made.[2] Theoretical analysis indicates KrF4 would have an approximately square planar molecular geometry.[2]

Krypton tetrafluoride
Identifiers
3D model (JSmol)
  • InChI=1S/F4Kr/c1-5(2,3)4
    Key: PLAFPZRFEDSAJL-UHFFFAOYSA-N
  • [Kr](F)(F)(F)F
Properties
F4Kr
Molar mass 159.792 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Synthesis

The claimed synthesis was by passing electric discharge through krypton-fluorine mixture:[3]

Kr + 2F2 → KrF4

Physical properties

The claimed compound formed white crystalline solid.[4] Thermally, it is less stable than XeF4.[5]

References
  1. O'Donnell, T. A. (8 June 2017). The Chemistry of Fluorine: Comprehensive Inorganic Chemistry. Elsevier. p. 1026. ISBN 978-1-4831-4642-3. Retrieved 28 March 2023.
  2. Dixon, David A.; Wang, Tsang-Hsiu; Grant, Daniel J.; Peterson, Kirk A.; Christe, Karl O.; Schrobilgen, Gary J. (2007). "Heats of Formation of Krypton Fluorides and Stability Predictions for KrF4 and KrF6 from High Level Electronic Structure Calculations". Inorg. Chem. 46 (23): 10016–10021. doi:10.1021/ic701313h. PMID 17941630.
  3. Advanced Inorganic Chemistry Vol-1. Krishna Prakashan Media. p. 846. ISBN 978-81-87224-03-7. Retrieved 28 March 2023.
  4. Cotton, F. Albert (1964). Progress in Inorganic Chemistry, Volume 6. John Wiley & Sons. p. 260. ISBN 978-0-470-16657-4. Retrieved 28 March 2023.
  5. Grosse, A. V.; Kirshenbaum, A. D.; Streng, A. G.; Streng, L. V. (15 March 1963). "Krypton Tetrafluoride: Preparation and Some Properties". Science. 139 (3559): 1047–1048. Bibcode:1963Sci...139.1047G. doi:10.1126/science.139.3559.1047. PMID 17812982. Retrieved 28 March 2023.
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