Sodium deuteroxide

Sodium deuteroxide or deuterated sodium hydroxide is a chemical compound with the formula NaOD. It is a white solid very similar to sodium hydroxide, of which it is an isotopologue. It is used as a strong base and deuterium source in the production of other deuterated compounds. For example, reaction with chloral hydrate gives deuterated chloroform,[2] and reaction with n-nitrosodimethylamine gives the deuterated analog of that compound.[3]

Sodium deuteroxide[1]
Names
IUPAC name
Sodium deuteroxide
Other names
  • Deuterated sodium hydroxide
  • Sodium hydroxide-d
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 237-825-2
  • InChI=1S/Na.H2O/h;1H2/q+1;/p-1/i/hD
    Key: HEMHJVSKTPXQMS-DYCDLGHISA-M
  • [Na+].[O-][2H]
Properties
NaOD
Molar mass 41.003 g/mol
Appearance White solid
Soluble
Hazards
GHS labelling:
GHS05: Corrosive
Danger
H290, H314
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamond
3
0
1
Related compounds
Related compounds
 Sodium hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

References
  1. "Sodium deuteroxide". Sigma aldrich. Retrieved 30 April 2021.
  2. Breuer, F. W. (1935). "Chloroform-d (Deuteriochloroform)". Journal of the American Chemical Society. 57 (11): 2236–2237. doi:10.1021/ja01314a058.
  3. National Cancer Institute (U.S.) (1973). Journal (51 ed.). the University of Michigan.
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