Sodium diuranate

Sodium diuranate, also known as the yellow oxide of uranium, is an inorganic chemical compound with the chemical formula Na2U2O7. It is a sodium salt of a diuranate anion. It forms a hexahydrate Na2U2O7·6H2O. Sodium diuranate is commonly referred to by the initials SDU.[1] Along with ammonium diuranate it was a component in early yellowcakes.[2] The ratio of the two compounds is determined by process conditions; however, yellowcake is now largely a mix of uranium oxides.[3]

Sodium diuranate
Identifiers
ECHA InfoCard 100.033.882
UNII
Properties
Na2U2O7
Density 6.44 g/cm3
Melting point 1,646 °C (2,995 °F; 1,919 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Preparation

In the classical procedure for extracting uranium, pitchblende is broken up and mixed with sulfuric and nitric acids.[4] The uranium dissolves to form uranyl sulfate and sodium carbonate is added to precipitate impurities. If the uranium in the ore is in the tetravalent oxidation state, an oxidiser is added to oxidise it to the hexavalent oxidation state, and sodium hydroxide is then added to make the uranium precipitate as sodium diuranate.[5] The alkaline process of milling uranium ores involves precipitating sodium uranate from the pregnant leaching solution to produce the semi-refined product referred to as yellowcake.[6]

These older methods of extracting uranium from its uraninite ores has been replaced in current practice by such procedures as solvent extraction, ion exchange, and volatility methods.[7]

Sodium uranate may be obtained in the amorphous form by heating together urano-uranic oxide and sodium chlorate; or by heating sodium uranyl acetate or carbonate. The crystalline form is produced by adding the green oxide in small quantities to fused sodium chloride, or by dissolving the amorphous form in fused sodium chloride, and allowing crystallization to take place. It yields reddish-yellow to greenish-yellow prisms or leaflets.

Uses
A uranium glass bowl in the shape of a cat, on top of a fiestaware plate, both previous uses of Sodium diuranate.

In the past it was widely used to produce uranium glass or vaseline glass,[8] the sodium salt dissolving easily into the silica matrix during the firing of the initial melt.

It was also used in porcelain dentures to give them a fluorescence similar to that of natural teeth and once used in pottery to produce ivory to yellow shades in glazes.[9] It was added to these products as a mix with cerium oxide.[10] The final uranium composition was from 0.008 to 0.1% by weight uranium with an average of about 0.02%. The practice appears to have stopped in the late 1980s.

References
  1. Meredith, A. D.(2013). Modified Sodium Diuranate Process For the Recovery of Uranium From Uranium Hexafluoride Transport Cylinder Wash Solution. (Doctoral dissertation). Retrieved from http://scholarcommons.sc.edu/etd/2466
  2. James A. Kent (27 May 2010). Kent and Riegel's Handbook of Industrial Chemistry and Biotechnology. Springer Science & Business Media. pp. 962–. ISBN 978-0-387-27843-8.
  3. Hausen, D. M. (1998). "Characterizing and classifying uranium yellow cakes: A background". JOM. 50 (12): 45–47. Bibcode:1998JOM....50l..45H. doi:10.1007/s11837-998-0307-5. ISSN 1047-4838. S2CID 97023067.
  4. "MQes Uranium Inc". Retrieved 2016-06-01.
  5. Purification of sodium diuranate. Retrieved 2020-04-30
  6. Method of precipitation of sodium diuranate. Retrieved 2020-04-30
  7. Gindler, J. E.(1962) The Radiochemistry of Uranium pp 39-235
  8. Landa, E. R.; Disantis, D. J. (1993). "A brief history of radioactive glassware". Radiographics. 13 (3): 697–699. doi:10.1148/radiographics.13.3.8316677. PMID 8316677.
  9. "Uranium Containing Dentures (ca. 1960s, 1970s)". Retrieved 2016-06-01.
  10. Shcherbakov, Alexander B.; Reukov, Vladimir V.; Yakimansky, Alexander V.; Krasnopeeva, Elena L.; Ivanova, Olga S.; Popov, Anton L.; Ivanov, Vladimir K. (17 March 2021). "CeO2 Nanoparticle-Containing Polymers for Biomedical Applications: A Review". Polymers. 13 (6): 924. doi:10.3390/polym13060924. ISSN 2073-4360. PMC 8002506. PMID 33802821.
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