Sulfur dioxide

Sulfur dioxide
Names
IUPAC name
Sulfur dioxide
Other names
Sulfurous anhydride
Sulfur(IV) oxide
Identifiers
3D model (JSmol)
Beilstein Reference
 3535237
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.028.359
EC Number
  • 231-195-2
E number E220 (preservatives)
Gmelin Reference
 1443
KEGG
MeSH Sulfur+dioxide
RTECS number
  • WS4550000
UNII
UN number 1079, 2037
CompTox Dashboard (EPA)
  • InChI=1S/O2S/c1-3-2 Y
    Key: RAHZWNYVWXNFOC-UHFFFAOYSA-N Y
  • InChI=1/O2S/c1-3-2
    Key: RAHZWNYVWXNFOC-UHFFFAOYAT
  • O=S=O
Properties
SO
2
Molar mass 64.066 g mol−1
Appearance Colorless and pungent gas
Odor Pungent; similar to a just-struck match[1]
Density 2.6288 kg m−3
Melting point −72 °C; −98 °F; 201 K
Boiling point −10 °C (14 °F; 263 K)
94 g/L[2]
forms sulfurous acid
Vapor pressure 237.2 kPa
Acidity (pKa) ~1.81
Basicity (pKb) ~12.19
−18.2·10−6 cm3/mol
Viscosity 12.82 μPa·s[3]
Structure
C2v
Digonal
Molecular shape
 Dihedral
Dipole moment
 1.62 D
Thermochemistry
Std molar
entropy (S⦵298)
 248.223 J K−1 mol−1
−296.81 kJ mol−1
Hazards
GHS labelling:
Danger
Hazard statements
 H314, H331[4]
NFPA 704 (fire diamond)
3
0
0
Lethal dose or concentration (LD, LC):
3000 ppm (mouse, 30 min)
2520 ppm (rat, 1 hr)[5]
993 ppm (rat, 20 min)
611 ppm (rat, 5 hr)
764 ppm (mouse, 20 min)
1000 ppm (human, 10 min)
3000 ppm (human, 5 min)[5]
NIOSH (US health exposure limits):
PEL (Permissible)
 TWA 5 ppm (13 mg/m3)[6]
REL (Recommended)
 TWA 2 ppm (5 mg/m3) ST 5 ppm (13 mg/m3)[6]
IDLH (Immediate danger)
 100 ppm[6]
Related compounds
Related sulfur oxides
 Sulfur monoxide
Sulfur trioxide
Related compounds
 Ozone

Selenium dioxide
Sulfurous acid
Tellurium dioxide

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula SO
2. It is a toxic gas responsible for the smell of burnt matches. It is released naturally by volcanic activity and is produced as a by-product of copper extraction and the burning of sulfur-bearing fossil fuels. Sulfur dioxide has a pungent smell like nitric acid.

Structure and bonding

SO2 is a bent molecule with C2v symmetry point group. A valence bond theory approach considering just s and p orbitals would describe the bonding in terms of resonance between two resonance structures.

Two resonance structures of sulfur dioxide

The sulfur–oxygen bond has a bond order of 1.5. There is support for this simple approach that does not invoke d orbital participation.[7] In terms of electron-counting formalism, the sulfur atom has an oxidation state of +4 and a formal charge of +1.

Occurrence
The blue auroral glows of Io's upper atmosphere are caused by volcanic sulfur dioxide.

Sulfur dioxide is found on Earth and exists in very small concentrations and in the atmosphere at about 1 ppm.[8][9]

On other planets, sulfur dioxide can be found in various concentrations, the most significant being the atmosphere of Venus, where it is the third-most abundant atmospheric gas at 150 ppm. There, it reacts with water to form clouds of sulfuric acid, and is a key component of the planet's global atmospheric sulfur cycle and contributes to global warming.[10] It has been implicated as a key agent in the warming of early Mars, with estimates of concentrations in the lower atmosphere as high as 100 ppm,[11] though it only exists in trace amounts. On both Venus and Mars, as on Earth, its primary source is thought to be volcanic. The atmosphere of Io, a natural satellite of Jupiter, is 90% sulfur dioxide[12] and trace amounts are thought to also exist in the atmosphere of Jupiter.

As an ice, it is thought to exist in abundance on the Galilean moons—as subliming ice or frost on the trailing hemisphere of Io,[13] and in the crust and mantle of Europa, Ganymede, and Callisto, possibly also in liquid form and readily reacting with water.[14]

Production

Sulfur dioxide is primarily produced for sulfuric acid manufacture (see contact process). In the United States in 1979, 23.6 million metric tons (26 million U.S. short tons) of sulfur dioxide were used in this way, compared with 150,000 metric tons (165,347 U.S. short tons) used for other purposes. Most sulfur dioxide is produced by the combustion of elemental sulfur. Some sulfur dioxide is also produced by roasting pyrite and other sulfide ores in air.[15]

Combustion routes

Sulfur dioxide is the product of the burning of sulfur or of burning materials that contain sulfur:

S + O2 → SO2, ΔH = −297 kJ/mol

To aid combustion, liquified sulfur (140–150 °C, 284-302 °F) is sprayed through an atomizing nozzle to generate fine drops of sulfur with a large surface area. The reaction is exothermic, and the combustion produces temperatures of 1000–1600 °C (1832–2912 °F). The significant amount of heat produced is recovered by steam generation that can subsequently be converted to electricity.[15]

The combustion of hydrogen sulfide and organosulfur compounds proceeds similarly. For example:

2 H2S + 3 O2 → 2 H2O + 2 SO2

The roasting of sulfide ores such as pyrite, sphalerite, and cinnabar (mercury sulfide) also releases SO2:[16]

4 FeS2 + 11 O2 → 2 Fe2O3 + 8 SO2
2 ZnS + 3 O2 → 2 ZnO + 2 SO2
HgS + O2 → Hg + SO2
4 FeS + 7O2 → 2 Fe2O3 + 4 SO2

A combination of these reactions is responsible for the largest source of sulfur dioxide, volcanic eruptions. These events can release millions of tons of SO2.

Reduction of higher oxides

Sulfur dioxide can also be a byproduct in the manufacture of calcium silicate cement; CaSO4 is heated with coke and sand in this process:

2 CaSO4 + 2 SiO2 + C → 2 CaSiO3 + 2 SO2 + CO2

Until the 1970s, commercial quantities of sulfuric acid and cement were produced by this process in Whitehaven, England. Upon being mixed with shale or marl, and roasted, the sulfate liberated sulfur dioxide gas, used in sulfuric acid production, the reaction also produced calcium silicate, a precursor in cement production.[17]

On a laboratory scale, the action of hot concentrated sulfuric acid on copper turnings produces sulfur dioxide.

Cu + 2 H2SO4 → CuSO4 + SO2 + 2 H2O

From sulfites

Sulfites results by the action of aqueous base on sulfur dioxide:

SO2 + 2 NaOH → Na2SO3 + H2O

The reverse reaction occurs upon acidification:

H+ + HSO3− → SO2 + H2O

Reactions

Featuring sulfur in the +4 oxidation state, sulfur dioxide is a reducing agent. It is oxidized by halogens to give the sulfuryl halides, such as sulfuryl chloride:

SO2 + Cl2 → SO2Cl2

Sulfur dioxide is the oxidising agent in the Claus process, which is conducted on a large scale in oil refineries. Here, sulfur dioxide is reduced by hydrogen sulfide to give elemental sulfur:

SO2 + 2 H2S → 3 S + 2 H2O

The sequential oxidation of sulfur dioxide followed by its hydration is used in the production of sulfuric acid.

2 SO2 + 2 H2O + O2 → 2 H2SO4

Laboratory reactions

Sulfur dioxide is one of the few common acidic yet reducing gases. It turns moist litmus pink (being acidic), then white (due to its bleaching effect). It may be identified by bubbling it through a dichromate solution, turning the solution from orange to green (Cr3+ (aq)). It can also reduce ferric ions to ferrous.[18]

Sulfur dioxide can react with certain 1,3-dienes in a cheletropic reaction to form cyclic sulfones. This reaction is exploited on an industrial scale for the synthesis of sulfolane, which is an important solvent in the petrochemical industry.

Sulfur dioxide can bind to metal ions as a ligand to form metal sulfur dioxide complexes, typically where the transition metal is in oxidation state 0 or +1. Many different bonding modes (geometries) are recognized, but in most cases, the ligand is monodentate, attached to the metal through sulfur, which can be either planar and pyramidal η1.[19] As a η1-SO2 (S-bonded planar) ligand sulfur dioxide functions as a Lewis base using the lone pair on S. SO2 functions as a Lewis acids in its η1-SO2 (S-bonded pyramidal) bonding mode with metals and in its 1:1 adducts with Lewis bases such as dimethylacetamide and trimethyl amine. When bonding to Lewis bases the acid parameters of SO2 are EA = 0.51 and EA = 1.56.

Uses

The overarching, dominant use of sulfur dioxide is in the production of sulfuric acid.[15]

Precursor to sulfuric acid

Sulfur dioxide is an intermediate in the production of sulfuric acid, being converted to sulfur trioxide, and then to oleum, which is made into sulfuric acid. Sulfur dioxide for this purpose is made when sulfur combines with oxygen. The method of converting sulfur dioxide to sulfuric acid is called the contact process. Several billion kilograms are produced annually for this purpose.

Food preservative

Sulfur dioxide is sometimes used as a preservative for dried apricots, dried figs, and other dried fruits, owing to its antimicrobial properties and ability to prevent oxidation,[20] and is called E220[21] when used in this way in Europe. As a preservative, it maintains the colorful appearance of the fruit and prevents rotting. It is also added to sulfured molasses. Sublimed sulfite is ignited and burned in an enclosed space with the fruits. This is usually done outdoors.[22] Fruits may be sulfured by dipping them into an either sodium bisulfite, sodium sulfite or sodium metabisulfite.[22]

Winemaking

Sulfur dioxide was first used in winemaking by the Romans, when they discovered that burning sulfur candles inside empty wine vessels keeps them fresh and free from vinegar smell.[23]

It is still an important compound in winemaking, and is measured in parts per million (ppm) in wine. It is present even in so-called unsulfurated wine at concentrations of up to 10 mg/L.[24] It serves as an antibiotic and antioxidant, protecting wine from spoilage by bacteria and oxidation - a phenomenon that leads to the browning of the wine and a loss of cultivar specific flavors.[25][26] Its antimicrobial action also helps minimize volatile acidity. Wines containing sulfur dioxide are typically labeled with "containing sulfites".

Sulfur dioxide exists in wine in free and bound forms, and the combinations are referred to as total SO2. Binding, for instance to the carbonyl group of acetaldehyde, varies with the wine in question. The free form exists in equilibrium between molecular SO2 (as a dissolved gas) and bisulfite ion, which is in turn in equilibrium with sulfite ion. These equilibria depend on the pH of the wine. Lower pH shifts the equilibrium towards molecular (gaseous) SO2, which is the active form, while at higher pH more SO2 is found in the inactive sulfite and bisulfite forms. The molecular SO2 is active as an antimicrobial and antioxidant, and this is also the form which may be perceived as a pungent odor at high levels. Wines with total SO2 concentrations below 10 ppm do not require "contains sulfites" on the label by US and EU laws. The upper limit of total SO2 allowed in wine in the US is 350 ppm; in the EU it is 160 ppm for red wines and 210 ppm for white and rosé wines. In low concentrations, SO2 is mostly undetectable in wine, but at free SO2 concentrations over 50 ppm, SO2 becomes evident in the smell and taste of wine.

SO2 is also a very important compound in winery sanitation. Wineries and equipment must be kept clean, and because bleach cannot be used in a winery due to the risk of cork taint,[27] a mixture of SO2, water, and citric acid is commonly used to clean and sanitize equipment. Ozone (O3) is now used extensively for sanitizing in wineries due to its efficacy, and because it does not affect the wine or most equipment.[28]

As a reducing agent

Sulfur dioxide is also a good reductant. In the presence of water, sulfur dioxide is able to decolorize substances. Specifically, it is a useful reducing bleach for papers and delicate materials such as clothes. This bleaching effect normally does not last very long. Oxygen in the atmosphere reoxidizes the reduced dyes, restoring the color. In municipal wastewater treatment, sulfur dioxide is used to treat chlorinated wastewater prior to release. Sulfur dioxide reduces free and combined chlorine to chloride.[29]

Sulfur dioxide is fairly soluble in water, and by both IR and Raman spectroscopy; the hypothetical sulfurous acid, H2SO3, is not present to any extent. However, such solutions do show spectra of the hydrogen sulfite ion, HSO3−, by reaction with water, and it is in fact the actual reducing agent present:

SO2 + H2O ⇌ HSO3− + H+

As a fumigant

In the beginning of the 20th century, sulfur dioxide was used in Buenos Aires as a fumigant to kill rats that carried the Yersinia pestis bacterium, which causes bubonic plague. The application was successful, and the application of this method was extended to other areas in South America. In Buenos Aires, where these apparatuses were known as Sulfurozador, but later also in Rio de Janeiro, New Orleans and San Francisco, the sulfur dioxide treatment machines were brought into the streets to enable extensive disinfection campaigns, with effective results.[30]

Biochemical and biomedical roles

Sulfur dioxide or its conjugate base bisulfite is produced biologically as an intermediate in both sulfate-reducing organisms and in sulfur-oxidizing bacteria, as well. The role of sulfur dioxide in mammalian biology is not yet well understood.[31] Sulfur dioxide blocks nerve signals from the pulmonary stretch receptors and abolishes the Hering–Breuer inflation reflex.

It is considered that endogenous sulfur dioxide plays a significant physiological role in regulating cardiac and blood vessel function, and aberrant or deficient sulfur dioxide metabolism can contribute to several different cardiovascular diseases, such as arterial hypertension, atherosclerosis, pulmonary arterial hypertension, and stenocardia.[32]

It was shown that in children with pulmonary arterial hypertension due to congenital heart diseases the level of homocysteine is higher and the level of endogenous sulfur dioxide is lower than in normal control children. Moreover, these biochemical parameters strongly correlated to the severity of pulmonary arterial hypertension. Authors considered homocysteine to be one of useful biochemical markers of disease severity and sulfur dioxide metabolism to be one of potential therapeutic targets in those patients.[33]

Endogenous sulfur dioxide also has been shown to lower the proliferation rate of endothelial smooth muscle cells in blood vessels, via lowering the MAPK activity and activating adenylyl cyclase and protein kinase A.[34] Smooth muscle cell proliferation is one of important mechanisms of hypertensive remodeling of blood vessels and their stenosis, so it is an important pathogenetic mechanism in arterial hypertension and atherosclerosis.

Endogenous sulfur dioxide in low concentrations causes endothelium-dependent vasodilation. In higher concentrations it causes endothelium-independent vasodilation and has a negative inotropic effect on cardiac output function, thus effectively lowering blood pressure and myocardial oxygen consumption. The vasodilating and bronchodilating effects of sulfur dioxide are mediated via ATP-dependent calcium channels and L-type ("dihydropyridine") calcium channels. Endogenous sulfur dioxide is also a potent antiinflammatory, antioxidant and cytoprotective agent. It lowers blood pressure and slows hypertensive remodeling of blood vessels, especially thickening of their intima. It also regulates lipid metabolism.[35]

Endogenous sulfur dioxide also diminishes myocardial damage, caused by isoproterenol adrenergic hyperstimulation, and strengthens the myocardial antioxidant defense reserve.[36]

As a reagent and solvent in the laboratory

Sulfur dioxide is a versatile inert solvent widely used for dissolving highly oxidizing salts. It is also used occasionally as a source of the sulfonyl group in organic synthesis. Treatment of aryl diazonium salts with sulfur dioxide and cuprous chloride yields the corresponding aryl sulfonyl chloride, for example:[37]

As a result of its very low Lewis basicity, it is often used as a low-temperature solvent/diluent for superacids like magic acid (FSO3H/SbF5), allowing for highly reactive species like tert-butyl cation to be observed spectroscopically at low temperature (though tertiary carbocations do react with SO2 above about –30 °C, and even less reactive solvents like SO2ClF must be used at these higher temperatures).[38]

As a refrigerant

Being easily condensed and possessing a high heat of evaporation, sulfur dioxide is a candidate material for refrigerants. Prior to the development of chlorofluorocarbons, sulfur dioxide was used as a refrigerant in home refrigerators.

Climate engineering

Injections of sulfur dioxide in the stratosphere has been proposed in climate engineering. The cooling effect would be similar to what has been observed after the large explosive 1991 eruption of Mount Pinatubo. However this form of geoengineering would have uncertain regional consequences on rainfall patterns, for example in monsoon regions.[39]

As an air pollutant
A collection of estimates of past and future anthropogenic global sulfur dioxide emissions. The Cofala et al. estimates are for sensitivity studies on SO2 emission policies, CLE: Current Legislation, MFR: Maximum Feasible Reductions. RCPs (Representative Concentration Pathways) are used in CMIP5 simulations for latest (2013–2014) IPCC 5th assessment report.

Sulfur dioxide is a noticeable component in the atmosphere, especially following volcanic eruptions.[40] According to the United States Environmental Protection Agency (EPA),[41] the amount of sulfur dioxide released in the U.S. per year was:

Year SO2
1970 31,161,000 short tons (28.3 Mt)
1980 25,905,000 short tons (23.5 Mt)
1990 23,678,000 short tons (21.5 Mt)
1996 18,859,000 short tons (17.1 Mt)
1997 19,363,000 short tons (17.6 Mt)
1998 19,491,000 short tons (17.7 Mt)
1999 18,867,000 short tons (17.1 Mt)

Sulfur dioxide is a major air pollutant and has significant impacts upon human health.[42] In addition, the concentration of sulfur dioxide in the atmosphere can influence the habitat suitability for plant communities, as well as animal life.[43] Sulfur dioxide emissions are a precursor to acid rain and atmospheric particulates. Due largely to the US EPA's Acid Rain Program, the U.S. has had a 33% decrease in emissions between 1983 and 2002. This improvement resulted in part from flue-gas desulfurization, a technology that enables SO2 to be chemically bound in power plants burning sulfur-containing coal or oil. In particular, calcium oxide (lime) reacts with sulfur dioxide to form calcium sulfite:

CaO + SO2 → CaSO3

Aerobic oxidation of the CaSO3 gives CaSO4, anhydrite. Most gypsum sold in Europe comes from flue-gas desulfurization.

To control sulfur emissions, dozens of methods with relatively high efficiencies have been developed for fitting of coal-fired power plants.[44]

Sulfur can be removed from coal during burning by using limestone as a bed material in fluidized bed combustion.[45]

Sulfur can also be removed from fuels before burning, preventing formation of SO2 when the fuel is burnt. The Claus process is used in refineries to produce sulfur as a byproduct. The Stretford process has also been used to remove sulfur from fuel. Redox processes using iron oxides can also be used, for example, Lo-Cat[46] or Sulferox.[47]

An analysis found that 18 coal-fired power stations in the western Balkans emitted two-and-half times more sulphur dioxide than all 221 coal plants in the EU combined.[48]

Fuel additives such as calcium additives and magnesium carboxylate may be used in marine engines to lower the emission of sulfur dioxide gases into the atmosphere.[49]

As of 2006, China was the world's largest sulfur dioxide polluter, with 2005 emissions estimated to be 25,490,000 short tons (23.1 Mt). This amount represents a 27% increase since 2000, and is roughly comparable with U.S. emissions in 1980.[50]

  • A sulfur dioxide plume from Halemaʻumaʻu, which glows at night
  • Sulfur dioxide in the world on April 15, 2017. Note that sulfur dioxide moves through the atmosphere with prevailing winds and thus local sulfur dioxide distributions vary day to day with weather patterns and seasonality.

Safety
US Geological Survey volunteer tests for sulfur dioxide after the 2018 lower Puna eruption.

Inhalation

Incidental exposure to sulfur dioxide is routine, e.g. the smoke from matches, coal, and sulfur-containing fuels.

Sulfur dioxide is mildly toxic and can be hazardous in high concentrations.[51] Long-term exposure to low concentrations is also problematic. A 2011 systematic review concluded that exposure to sulfur dioxide is associated with preterm birth.[52]

U.S. regulations

In 2008, the American Conference of Governmental Industrial Hygienists reduced the short-term exposure limit to 0.25 parts per million (ppm). In the US, the OSHA set the PEL at 5 ppm (13 mg/m3) time-weighted average. Also in the US, NIOSH set the IDLH at 100 ppm.[53] In 2010, the EPA "revised the primary SO2 NAAQS by establishing a new one-hour standard at a level of 75 parts per billion (ppb). EPA revoked the two existing primary standards because they would not provide additional public health protection given a one-hour standard at 75 ppb."[42]

Ingestion

In the United States, the Center for Science in the Public Interest lists the two food preservatives, sulfur dioxide and sodium bisulfite, as being safe for human consumption except for certain asthmatic individuals who may be sensitive to them, especially in large amounts.[54] Symptoms of sensitivity to sulfiting agents, including sulfur dioxide, manifest as potentially life-threatening trouble breathing within minutes of ingestion.[55] Sulphites may also cause symptoms in non-asthmatic individuals, namely dermatitis, urticaria, flushing, hypotension, abdominal pain and diarrhea, and even life-threatening anaphylaxis.[56]

See also

References
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